The Argentine international centre-half played 90 minutes in defence for the Spanish side as they travelled to Espanyol in La Liga.
He ended up on the losing side, however, with the hosts claiming a 1-0 win.
Elsewhere on the same day, Dominic Ball went on as a substitute on the hour mark for Rangers in their eventual 2-2 draw at St Mirren in the Scottish Championship. The two sides were level at 1-1 at the time of his introduction but late goals apiece meant the spoils were still shared at the full-time whistle.
On Saturday, DeAndre Yedlin was once again on duty at right-back for Sunderland as they snatched a 1-1 draw away at Stoke City in the Premier League.
Also that afternoon, Grant Ward played 90 minutes in midfield for Rotherham United as they lost 1-0 at home to Blackburn Rovers in the Championship.