Andy Barcham and Jamie O'Hara also netted two goals each as the lads looked determined to impress Clive Allen and get back to winning ways following last week's disappointing defeat at Dover Athletic.
The result was never in doubt once Daniels tucked his first away with three minutes on the clock and it was relentless stuff from the first to last whistle at Park Lane.
Daniels and O'Hara pulled the strings in the first half and Daniels was eventually involved in six goals, scoring three and setting up another three.
Barnard - back after a slight ankle injury - claimed his first to make it five just before half-time and took over in the second half, grabbing a hat-trick, the last aptly from Daniels' cross.
Barcham and O'Hara produced clinical finishes for their goals and on top of the goals, there was important game time at this level for first year Academy players Richard Stroud in goal - he was then replaced by 16-year-old James Dalton - Jake Livermore, David Hutton and Takura Mtandari.
THE KEY ACTION...
3mins: GOAL - SPURS. Barnard touch released Daniels, cut into box from the left, tidy finish low into the bottom corner from 18 yards.
Canvey Island 0, Spurs XI 1
4mins: CHANCE. Barnard found a yard of space in the box, 12 yards out, screwed shot just wide as challenge came in.
6mins: Daniels tucked pass inside to O'Hara, 18 yards out, managed to get decent strike on goal as he was clattered by West but no problem for Wiseman.
9mins: CLOSE. Rugg run to the byline, right side, fizzed low cross to near post that Gordon missed in front of goal.
12mins: SAVE. O'Hara split defence with perfect pass from half-way for Barcham to run onto, one-on-one chance, Wiseman out quickly to smother.
13mins: CLOSE. Rugg dipping volley from 25 yards sailed a couple of yards wide.
14mins: GOAL - SPURS. Maghoma broke down the right and spotted Daniels in yards of space far post, measured low cross slotted away by Daniels in style from eight yards.
Canvey Island 0, Spurs XI 2
17mins: GOAL - SPURS. Daniels on the ball again, this time infield, rolled it into the path of O'Hara who struck sweet shot into bottom corner from 25 yards.
Canvey Island 0, Spurs XI 3
18mins: GOAL - SPURS - DANIELS HAT-TRICK. O'Hara burst from midfield into the box, Wiseman out to make a fine save but loose ball rolled outside his box to Daniels who picked his spot with his right foot from 20 yards, in off the post.
Canvey Island 0, Spurs XI 4
19mins: SAVE. Lewis this time cut through the middle of the home defence, one-on-one chance, Wiseman saved with legs.
24mins: Good build-up ended with Daniels crossing for Lewis to hit volley into the ground straight at Wiseman.
27mins: Gordon fed in down right channel of area, flashed shot across goal.
33mins: Daniels attempted ambitious volley on the turn from 20 yards that sailed into the car park.
38mins: Ifil drilled 30-yarder wide.
42mins: Barnard released Daniels down the left, beat his man and picked our O'Hara on the edge of the box, first-time volley high and wide.
Added time: GOAL - SPURS. O'Hara's corner hit on the volley by Defendi, definitely took a deflection on the way in - Barnard claimed it was off him, and therefore claimed it!
Canvey Island 0, Spurs XI 5
Half-time: Canvey Island 0, Spurs XI 5
Half-time: SUB. Hughton for Lee.
49mins: GOAL - SPURS. Hughton fed ball into Barcham, controlled well and dinked lovely finish over Wiseman.
Canvey Island 0, Spurs XI 6
50mins: CHANCE. Corbell climbed high to meet Gordon's corner but headed over from close range.
56mins: SAVE. Maghoma run centrally before pushing ball left for Barnard to curl effort from 20 yards, Wiseman at full stretch made fine diving save.
59mins: SUBS. Dalton, Mtandari and Hutton for Stroud, Riley and Maghoma.
65mins: SAVE. Barnard prodded Lewis' cross towards goal from six yards but Wiseman managed to block with legs.
68mins: SAVE. Great run from Hutton cutting in from right, tried curler from 22 yards that Wiseman saved at full stretch to his left.
72mins: GOAL - SPURS. Barcham did all the hard work, beat his man and hit the byline, right channel of box, low cross to far post finished clinically by O'Hara.
Canvey Island 0, Spurs XI 7
78mins: GOAL. Lewis played in Barcham, he beat West before slotting into corner.
Canvey Island 0, Spurs XI 8
78mins: SUB. Livermore for Lewis.
83mins: GOAL - SPURS. Daniels played in Barnard, left channel, side-footed across Wiseman into corner.
Canvey Island 0, Spurs XI 9
84mins: PENALTY/GOAL - SPURS - BARNARD HAT-TRICK. Hutton cut in from right and played through for Barnard who was upended in box. Barnard picked himself up to convert from the spot for his hat-trick.
Canvey Island 0, Spurs XI 10
89mins: GOAL - SPURS. Best move of the night involving Hutton, Livermore and eventually Daniels drilling in low cross to the near post that Barnard converted sliding in from six yards.
Canvey Island 0, Spurs XI 11
Canvey Island: Wiseman, Blewer (Lamb, 72), Bourne (Stuart, 80), West (Davidson, 80), Kreyling (Wall, 46), Dobinson (Corbell, 34), Eedgar, Roberts, Rugg, Gordon (Batch, 59), Jay. Unused subs: Holmes, Johnson, Reade.
Spurs XI: Stroud (Dalton, 59), Riley (Mtandari, 59), Ifil, Lewis (Livermore, 78), Lee (Hughton, 46), Defendi, Maghoma (Hutton, 59), O'Hara, Barnard, Barcham, Daniels. Unused subs: Fraser-Allen, Suckling.
Lee Barnard bagged four goals and Charlie Daniels hit an 18-minute hat-trick as our Spurs XI scored XI at Canvey Island on Monday night.